2022-07-12
近年来,大多数的(de)电(dian)(dian)(dian)子产品都使(shi)用锂(li)电(dian)(dian)(dian)池(chi)(chi)(chi)作为主要(yao)电(dian)(dian)(dian)源,锂(li)电(dian)(dian)(dian)池(chi)(chi)(chi)具有(you)体积小、能量密度高(gao)(gao)、无记忆效应(ying)、循环(huan)寿命高(gao)(gao)、自放电(dian)(dian)(dian)率低、电(dian)(dian)(dian)压高(gao)(gao)等特点(dian),但其与(yu)镍(nie)(nie)镉、镍(nie)(nie)氢电(dian)(dian)(dian)池(chi)(chi)(chi)不(bu)同,在(zai)(zai)充电(dian)(dian)(dian)和(he)放电(dian)(dian)(dian)时需要(yao)考虑(lv)安全性(xing),因此(ci),针(zhen)对锂(li)电(dian)(dian)(dian)池(chi)(chi)(chi)的(de)过充、放电(dian)(dian)(dian)、过流和(he)短(duan)路电(dian)(dian)(dian)流保(bao)护(hu)显(xian)得更为重(zhong)要(yao),因此(ci),通(tong)常在(zai)(zai)电(dian)(dian)(dian)池(chi)(chi)(chi)组中(zhong)设计保(bao)护(hu)电(dian)(dian)(dian)路对锂(li)电(dian)(dian)(dian)池(chi)(chi)(chi)进行保(bao)护(hu),这(zhei)说(shuo)明了锂(li)电(dian)(dian)(dian)池(chi)(chi)(chi)保(bao)护(hu)ic的(de)重(zhong)要(yao)性(xing)。
锂离子电(dian)池(chi)能量密(mi)度高,很难保证(zheng)(zheng)电(dian)池(chi)的(de)(de)(de)(de)安全。在(zai)过(guo)充(chong)电(dian)状态(tai)下,电(dian)池(chi)温度升高后(hou)能量会过(guo)剩(sheng),电(dian)解液(ye)分解成气体,内压(ya)升高而导致着火(huo)或破(po)裂。反之,在(zai)过(guo)度放电(dian)状态(tai)下,电(dian)解液(ye)的(de)(de)(de)(de)分解会导致电(dian)池(chi)特性(xing)和耐久(jiu)性(xing)的(de)(de)(de)(de)恶化(hua)。锂离子电(dian)池(chi)的(de)(de)(de)(de)保护(hu)电(dian)路(lu)就是为了保证(zheng)(zheng)这种过(guo)充(chong)放电(dian)状态(tai)的(de)(de)(de)(de)安全性(xing),防止特性(xing)恶化(hua)。
当锂电(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)过充(chong)(chong)(chong)电(dian)(dian)(dian)(dian)(dian)(dian)(dian),为了避(bi)免温度升高(gao)造(zao)成内压(ya)力升高(gao),需停止(zhi)充(chong)(chong)(chong)电(dian)(dian)(dian)(dian)(dian)(dian)(dian)状态(tai)。保护IC将检(jian)(jian)测电(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)电(dian)(dian)(dian)(dian)(dian)(dian)(dian)压(ya),当检(jian)(jian)测到(dao)过充(chong)(chong)(chong)电(dian)(dian)(dian)(dian)(dian)(dian)(dian)时(shi),过充(chong)(chong)(chong)电(dian)(dian)(dian)(dian)(dian)(dian)(dian)检(jian)(jian)测功率MOSFET将其关(guan)闭(bi),切断充(chong)(chong)(chong)电(dian)(dian)(dian)(dian)(dian)(dian)(dian)。在对(dui)电(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)充(chong)(chong)(chong)电(dian)(dian)(dian)(dian)(dian)(dian)(dian)时(shi),将电(dian)(dian)(dian)(dian)(dian)(dian)(dian)池(chi)充(chong)(chong)(chong)电(dian)(dian)(dian)(dian)(dian)(dian)(dian)到(dao)满(man)状态(tai)是(shi)用户非常关(guan)心的问题,同时(shi)也要考虑到(dao)安全问题,所以有(you)必要在达到(dao)允许(xu)电(dian)(dian)(dian)(dian)(dian)(dian)(dian)压(ya)时(shi)切断充(chong)(chong)(chong)电(dian)(dian)(dian)(dian)(dian)(dian)(dian)状态(tai)。
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锂(li)离(li)(li)(li)子电池的(de)电解质与其它电池的(de)有所不同,一般而言(yan)电解质是(shi)(shi)稳定的(de),但锂(li)离(li)(li)(li)子电池是(shi)(shi)特殊的(de)。在阳(yang)极上形成钝化膜称为固(gu)体电解质界(jie)面(SEI),其主要目(mu)的(de)是(shi)(shi)将阴阳(yang)两极隔(ge)开,但离(li)(li)(li)子仍能(neng)(neng)通过。薄(bo)膜不仅能(neng)(neng)让电池系统稳定,而且还能(neng)(neng)延长锂(li)离(li)(li)(li)子电池的(de)使用寿命(ming),但会对电池的(de)
铝壳电(dian)池(chi)在生(sheng)产过(guo)程(cheng)中可(ke)(ke)通过(guo)预化去(qu)除(chu)水(shui)(shui)、微(wei)量(liang)金(jin)(jin)属杂(za)质、微(wei)量(liang)元素等(deng)杂(za)质;金(jin)(jin)属反应(ying)电(dian)位(wei)可(ke)(ke)能(neng)相(xiang)对较低,含(han)量(liang)小(xiao),需要使用小(xiao)电(dian)流和电(dian)压的(de)判断;水(shui)(shui)份可(ke)(ke)以通过(guo)电(dian)化学(xue)分(fen)解(jie)将其除(chu)掉(diao)。铝壳电(dian)池(chi)通过(guo)做预化可(ke)(ke)以形成SEI膜(mo),SEI膜(mo)的(de)形成与电(dian)解(jie)质、负(fu)极(ji)以及预化的(de)设置密切相(xiang)关。
合(he)理(li)设(she)置锂电池(chi)正(zheng)(zheng)极(ji)、负(fu)极(ji)的(de)(de)配(pei)比(bi)系(xi)数是(shi)设(she)计电池(chi)时经常(chang)面(mian)临的(de)(de)问(wen)题(ti)(ti)(ti),今天小(xiao)编就(jiu)(jiu)来为(wei)大家详(xiang)细(xi)讲解这一问(wen)题(ti)(ti)(ti)。锂电池(chi)的(de)(de)正(zheng)(zheng)负(fu)极(ji)配(pei)比(bi),其实也(ye)是(shi)指负(fu)极(ji)的(de)(de)用量(liang)要多少(shao)才(cai)是(shi)合(he)适的(de)(de),量(liang)过多,就(jiu)(jiu)会浪费(fei),就(jiu)(jiu)需(xu)要提高正(zheng)(zheng)极(ji)的(de)(de)容量(liang),量(liang)少(shao),就(jiu)(jiu)会有析锂的(de)(de)问(wen)题(ti)(ti)(ti),正(zheng)(zheng)极(ji)容量(liang)难以(yi)发挥(hui),也(ye)就(jiu)(jiu)是(shi)人们常(chang)
锂(li)(li)离(li)(li)子(zi)电池(chi)(chi)介绍:锂(li)(li)离(li)(li)子(zi)电池(chi)(chi)是可充电电池(chi)(chi)的(de)(de)一(yi)种,主要依靠(kao)锂(li)(li)离(li)(li)子(zi)在正极(ji)和负极(ji)之(zhi)间移(yi)动(dong)来(lai)工作(zuo)。传统上,锂(li)(li)离(li)(li)子(zi)进(jin)入阴极(ji)材料的(de)(de)过(guo)程(cheng)(cheng)称(cheng)为(wei)(wei)嵌入,离(li)(li)开的(de)(de)过(guo)程(cheng)(cheng)称(cheng)为(wei)(wei)脱嵌。锂(li)(li)离(li)(li)子(zi)进(jin)入负极(ji)材料的(de)(de)过(guo)程(cheng)(cheng)称(cheng)为(wei)(wei)插入,离(li)(li)开的(de)(de)过(guo)程(cheng)(cheng)称(cheng)为(wei)(wei)脱插。像所有化学电池(chi)(chi)一(yi)样,锂(li)(li)离(li)(li)子(zi)电池(chi)(chi)由(you)3部(bu)分组成:
由于(yu)各锂电(dian)(dian)池(chi)(chi)厂商(shang)在生(sheng)(sheng)(sheng)产工艺和电(dian)(dian)池(chi)(chi)原材(cai)料(liao)配方上的差异,市场上的聚(ju)合物电(dian)(dian)池(chi)(chi)分为缠绕(rao)型和重叠型两(liang)种不同(tong)的结(jie)构。相反,越厚(hou)的液体锂电(dian)(dian)池(chi)(chi)越好(hao)生(sheng)(sheng)(sheng)产,小于(yu)4mm厚(hou)度的电(dian)(dian)池(chi)(chi)很难生(sheng)(sheng)(sheng)产,即使(shi)生(sheng)(sheng)(sheng)产出来,容量明显不如聚(ju)合物锂电(dian)(dian)池(chi)(chi),在成(cheng)本上也没有(you)优势。因此,电(dian)(dian)池(chi)(chi)越薄,聚(ju)合物生(sheng)(sheng)(sheng)
磷(lin)酸(suan)铁(tie)锂(li)电(dian)池(chi)泄漏的(de)原(yuan)因很多,所以泄漏的(de)情(qing)况不同,气味(wei)也不同。磷(lin)酸(suan)铁(tie)锂(li)电(dian)池(chi)电(dian)解液是碳(tan)(tan)酸(suan)烷(wan)基酯(zhi)加锂(li)盐(yan)、六氟(fu)磷(lin)酸(suan)锂(li)的(de)有(you)机溶(rong)(rong)剂,溶(rong)(rong)剂主要是碳(tan)(tan)酸(suan)乙烯酯(zhi)、碳(tan)(tan)酸(suan)二(er)甲酯(zhi),有(you)机溶(rong)(rong)剂有(you)一定毒(du)性(xing)。1、磷(lin)酸(suan)铁(tie)锂(li)电(dian)池(chi)的(de)过(guo)充电(dian)和过(guo)放电(dian)导致电(dian)池(chi)膨(peng)胀(zhang)过(guo)度和破裂。在这种情(qing)况下,由于电(dian)