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聚合物软包锂电池温度环境的适应情况

2022-03-14

聚合物软包锂电池

聚(ju)合物(wu)软(ruan)包锂(li)电(dian)池应用(yong)于(yu)不同(tong)环(huan)境(jing)时(shi)(shi)其(qi)安全使(shi)用(yong)极(ji)其(qi)重要,在众多因素(su)种,温(wen)度对电(dian)池的性能影(ying)响大。当(dang)环(huan)境(jing)温(wen)度降低(di)时(shi)(shi),电(dian)池内的化学反应也(ye)会(hui)(hui)随着降低(di),当(dang)电(dian)压(ya)保持(chi)恒(heng)定(ding)时(shi)(shi),其(qi)放电(dian)电(dian)流也(ye)会(hui)(hui)降低(di),终导(dao)致(zhi)功(gong)率降低(di)。当(dang)环(huan)境(jing)温(wen)度升(sheng)高时(shi)(shi),情况(kuang)正好相(xiang)反,电(dian)池功(gong)率上升(sheng)。同(tong)时(shi)(shi)温(wen)度也(ye)会(hui)(hui)影(ying)响电(dian)解液(ye)的转(zhuan)移(yi)速率以(yi)及(ji)电(dian)池的充放电(dian)性能,从而会(hui)(hui)破坏聚(ju)合物(wu)软(ruan)包锂(li)电(dian)池内的化学平衡。

聚合物软包锂(li)电(dian)(dian)池(chi)的(de)储存温(wen)度(du)一(yi)般为常(chang)温(wen)25±5℃。温(wen)度(du)影(ying)响锂(li)离子的(de)活性。温(wen)度(du)越(yue)高,活性越(yue)高,但(dan)温(wen)度(du)超过(guo)60℃时,极大(da)可能对电(dian)(dian)池(chi)内的(de)隔膜造(zao)成不可逆的(de)损坏,导致电(dian)(dian)池(chi)损坏。温(wen)度(du)过(guo)低,锂(li)离子活性降(jiang)低,电(dian)(dian)池(chi)容(rong)量无法(fa)释放,导致电(dian)(dian)池(chi)没(mei)电(dian)(dian),但(dan)当温(wen)度(du)恢复(fu)到(dao)常(chang)温(wen)时,电(dian)(dian)池(chi)容(rong)量则恢复(fu)正常(chang)。

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