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锂电池负极与电解质的反应

2022-09-14

锂电池

锂电(dian)池(chi)负极的碳(tan)材料在电(dian)池(chi)次充(chong)放电(dian)时(shi)不可(ke)避免地会(hui)与电(dian)解质发生反应。这一过程对锂电(dian)池(chi)的影响:

1、如(ru)果碳负极(ji)的(de)结构(gou)被破(po)坏,反(fan)应(ying)将导致碳材料结构(gou)的(de)变(bian)化

2、保护(hu)碳材料(liao)表面(mian),即在碳负极表面(mian)(固体界面(mian))形(xing)成钝(dun)化膜或SEI膜

电(dian)解液对负(fu)碳的三种不同反应

还原反应的(de)破坏(huai)和保护(hu)

溶剂化锂(li)离(li)(li)子(zi)通过(guo)电(dian)极/电(dian)解(jie)液液界面,直接(jie)进入碳材料层(ceng)。溶剂分(fen)(fen)子(zi)在(zai)较低电(dian)位的(de)(de)还原(yuan)分(fen)(fen)解(jie)层(ceng)下嵌入层(ceng),在(zai)石(shi)墨(mo)层(ceng)之间(jian)产(chan)(chan)生(sheng)锂(li)盐(yan)沉淀,并在(zai)碳材料结(jie)构中产(chan)(chan)生(sheng)大(da)量气(qi)体,由溶剂化层(ceng)中的(de)(de)锂(li)离(li)(li)子(zi)在(zai)碳负(fu)极表面产(chan)(chan)生(sheng)电(dian)子(zi)和还原(yuan)分(fen)(fen)解(jie)反(fan)应,使该过(guo)程中也有锂(li)和气(qi)体的(de)(de)生(sheng)成,但(dan)产(chan)(chan)生(sheng)的(de)(de)锂(li)介质会(hui)沉积在(zai)碳负(fu)极表面形成钝化膜,阻碍溶剂嵌入还原(yuan)。


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